THE STRUCTURE OF THERMOLUMINESCENCE TRAPS IN AQUEOUS GROWN KCl
Main Article Content
Abstract
The results of TL studies in aqueous grown undoped KCl crystals are reported. A de-convolution of TL curve into five component peaks has been performed and trap depths have been obtained. The importance of bi-vacancy has been established as a fundamental trap and its anion vacancy end has also been proposed as a suitable trap for thermoluminescence in KCl crystals. The traps at anion vacancies linked to impurity vacancy I-V pairs have also been envisaged and the shift in the depths of traps is attributed to the electric field of I-V pairs in the lattice caused by inherent divalent ions. Some traps linked to hydroxyl groups have also been identified.
Downloads
Article Details
Licensee MJS, Universiti Malaya, Malaysia. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
References
Ausin, V. & Rivas, J. A. (1972). Thermoluminescence and annealing of F-centres in KCl gamma irradiated at room temperature. Journal of Physics C: Solid State Physics, 5(1), 82-96.
Benia, H. M., Myrach, P., Gonchar, A., Risse, T., Nilius, N., & Freund, H. J. (2010). Electron trapping in misfit dislocations of MgO thin films. Physical Review B, 81(24), 241415.
Bos, A. J. J. (2006). Theory of thermoluminescence. Radiation measurements, 41, 545-556.
Bushnell, J. C. (1964). Electron-Nuclear Double Resonance Study of Z (1)-Centers in Potassium-Chloride (Doctoral dissertation, University of Illinois at Urbana-Champaign).
Davydov, A. S. (1965). Quantum Mechanics, Pergamon, London.
Deshmukh, B. T., &Moharil, S. V. (1985). Thermoluminescence of alkali halides doped with alkaline earth impurities. Bulletin of Materials Science, 7(5), 427-457.
Dhar, A., de Werd, L. A. and Stoebe, T.G., (1973), “Effects of Annhealing and coding processes onThermoluminiscence of LiF”Health Physics, 25, 427.
Furetta, C., Laudadio, M.T., Sanipoli, C., Scacco, A., Gomez-Ros, J. M. and Correcher, V. (1999), Thermoluminescence of OH- doped rubidium halides, J. Phys. Chem. Solids 60, 957-963.
Gourary, B. S., & Adrian, F. J. (1957). Approximate wave functions for the F center and their application to the electron spin resonance problem. Physical Review, 105(4), 1180.
Herman, Z. S., & Barnett, G. (1982). The Electronic Structure of F-Centres in Alkali Halide Crystals. RevistaBrasileira de Fisica, 12(1), 73-91.
Hoya, J., Laborde, J. I., Richard, D.&Renteria, (2017), M., Comp. Mat. Sc.,“Ab-initio study of F-centers in Alkali Halides”, 138, 1-7.
Jain, S. C., &Mehendru, P. C. (1965). Evidence of Different Types of F Centers from Thermoluminescence Studies in X-Irradiated Alkali Halides. I. Highly Pure KCl Crystals. Physical Review, 140(3A), A957.
Mehendru, P.C. and Radhakrishna, S. (1969), Thermoluminescence of pure and impurity doped KBr and NaCl crystals, J. Phys. C (Solid State), 2, 796-801.
Ortiz, A., Ramos – Bennal S., Negron – Mendoza A., Martinez, T. and Sanchez – Mejorada, G., Optical and thermoluminescence properties of a NaCl crystal doped with Cd2+, Mn2+ and exposed to gamma rays, J. RadioanalyticalNucl. Chem., 273, 573 – 575.
Puchalska, M and Bilski, P., (2005). “TL glow curve analysis using glow fit, the new powerful tool for deconvolution” Polish academy of sciences, Krakow, TCC Report No. 1968/d.
Pandey, M., Mishra, A. K., Pant, N. &Pandey, S. D. (2017). Thermoluminescence of undoped and Mn2+ doped KCl. ActaCiencia India, 43P, 255-260.
Pandey, Ruchi, Pandey, S D, Kumar, S. and Kumar, R., (2021), Stability of bi-vacancy trap for TL emission in KCl, Malaysian J. Sci., 40, 46-53.
Sastry, S.B.S. &Sapru (1979), TL glow and emission studies on suprapureRbBr irradiated at room temperature, phys. stat. sol. 94, K149-154.
Srivastava, J. P. (2008). Solid State Physics. Prentice Hall, New Delhi, India.
Stoebe, T. G. and de Werd, L. A., (1985), J.Appl. Phys., “Role of hydroxide impurity in the Thermoluminiscence behavior of LiF”, 57, 2217.
Wosiński, T. (1989). Evidence for the electron traps at dislocations in GaAs crystals. Journal of applied physics, 65(4), 1566-1570.